A smooth homomorphism of Lie groups has differential at the identity. Differentiating makes the corresponding left-invariant vector fields -related. Their commutator action on pulled-back functions shows that the differential of a Lie group homomorphism preserves Lie brackets. The map need not be injective or surjective.
An isomorphism of Lie groups is a group isomorphism that is also a diffeomorphism. Both the homomorphism and its inverse preserve the smooth structures. Its identity differential is a Lie algebra isomorphism, but an isomorphism of Lie algebras determines a global Lie group isomorphism without extra period data only for connected simply connected groups.
A Lie group homomorphism intertwines one-parameter subgroups and therefore obeys the displayed identity. A connected Lie group is generated by an identity neighbourhood in an exponential chart, so its homomorphism is uniquely determined by the differential at the identity. On a disconnected group, only the restriction to its identity component is determined this way; the images of the other components require extra data.
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