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An edge colouring assigns a label called a colour to every edge of a graph: it is a function $c:E(G)\to \{1,\dots ,k\}$. Here this definition allows arbitrary assignments. Two edges sharing a vertex may receive the same colour. A proper edge colouring imposes the additional condition that such edges receive different colours. Some textbooks use "edge colouring" as shorthand for this proper version; check the convention before applying a theorem.^[ref]

The distinction matters in Ramsey theory. In a red-blue edge colouring of a complete graph, a triangle in a graph is monochromatic when its three edges have the same colour. These are arbitrary edge colourings: forbidding equal colours on edges sharing a vertex would forbid the very monochromatic triangles in a graph being sought. For example, assigning red to every edge of $K_3$ is a valid arbitrary edge colouring, although it is not a proper edge colouring. Colour labels can also stand for time slots: then proper edge colouring turns incompatible jobs into separate rounds.

A proper edge colouring gives different labels to any two distinct edges sharing a vertex. We work with finite undirected graphs without self-loops; distinct parallel edges in a multigraph must also have different colours. For a simple graph, whose edges are two-element sets, the condition isEvery colour class $M_i=\{e\in E(G):c(e)=i\}$ is a matching in a graph. Conversely, a set partition of the edges into matchings in a graph supplies a proper edge colouring. Thus minimizing colours means grouping all the edges into as few matchings in a graph as possible.

The line graph makes the relationship with proper vertex colouring explicit: replace each original edge by a vertex, joining two new vertices exactly when their original edges share an endpoint. A proper edge colouring of $G$ becomes a proper vertex colouring of its line graph $L(G)$, so $\chi \prime (G)=\chi (L(G))$. For a multigraph, retain a distinct new vertex for each parallel edge.^[ref]