Line tension ($\gamma$)

Line tension is energy per unit length of a boundary, such as the edge between two phases of a lipid bilayer. Positive line tension tends to minimize the perimeter at fixed domain area. Its dimensions and geometry differ from surface tension, which is energy per unit area.

For a circular domain of radius $R_0$ with line tension $\gamma$, the stiffness of a real polar sine or cosine amplitude with integer angular harmonic $m$ is $K_m=\pi \gamma (m^2-1)/R_0$, when the enclosed area is fixed. The equipartition theorem gives $⟨u_m^2⟩=k_{B}T{R}_0/[\pi \gamma (m^2-1)]$ for $m\ge 2$. A positive-frequency complex Fourier mode coefficient has half this variance. The uniform mode is forbidden and $m=1$ is translation.

The first polar sine and cosine harmonics of a circular boundary represent displacements of its centre. A complete translation leaves perimeter and area unchanged, so line tension supplies zero stiffness to these modes. The centre of an unconfined domain has no normalizable positional thermal equilibrium in an infinite plane; recentering the boundary removes this freedom from a shape spectrum.