Mark S. Wrighton coauthored isolation and characterization of a photogenerated, carbonyl-bridged iron dimer with a triplet ground state. Structural and magnetic measurements jointly constrain its electronic description.
The example illustrates a limit of simple electron counting: an eighteen-electron formal count does not by itself prove that every multinuclear complex must have a closed-shell singlet ground state.[ref]
Figure 1.
Portrait of Mark S. Wrighton
. Tingyanxjtu; extracted from 4-美国圣路易斯华盛顿大学签约.jpg. CC BY-SA 4.0, via Wikimedia Commons. Source.

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