In the class order , the 15 Cartesian nuclear displacements of methane have characters . Only nuclei left fixed by an operation contribute to that operation's trace. Subtract translations and rotations to obtain the methane normal-mode representationIts dimension is . There are four frequency families: a nondegenerate symmetric stretch, a doubly degenerate bend, and triply degenerate stretch and bend modes.
The relevant decomposition is unchanged:Thus the same and vibrational symmetries are linearly Jahn-Teller active. Their coupling constants and the resulting energy surface can differ from those of a state. The ground-geometry methane normal-mode representation and the symmetry-allowed harmonic invariants are also unchanged; actual force constants in the excited state need not have the same values.