Under the standard smooth manifold hypotheses, the first answer is yes, although the isomorphism requires a choice. A partition of unity combines Euclidean inner products in manifold charts to produce a Riemannian metric . Nonnegative local weights summing to one preserve positivity, and local finiteness preserves smoothness. The musical isomorphism is
It is smooth and fiberwise invertible, with inverse having local matrix . It is therefore a vector bundle isomorphism. There is no preferred such map before a metric or equivalent additional structure is chosen.
The second answer is no. On , compare the trivial vector bundle with the Möbius line bundle
Both have rank one. A continuous section of a vector bundle of is represented on by a continuous function satisfying . If it were nowhere zero, the intermediate value theorem would prevent its endpoint signs from being opposite. Thus has no nowhere-zero section. The trivial bundle has the section , and a bundle isomorphism would carry that section to a nowhere-zero section of , a contradiction. Hence