Jeans escape is loss from the high-speed tail of a nearly Maxwell-Boltzmann velocity distribution near the exobase. It is sensitive to the escape parameter and favors light species in a hot, weakly bound atmosphere.
Hydrodynamic escape occurs when strong XUV heating drives a bulk outflow, which can entrain heavier species. An illustrative energy-limited scale is when the absorption and planet radii are comparable; efficiency, radiative losses and recombination can invalidate that simple limit.
Roche-lobe overflow removes gas through the low effective-potential barrier toward the inner Lagrange point when the extended atmosphere approaches the Roche lobe. Tides can also assist a wind before actual overflow.
Nonthermal atmospheric escape includes ion pickup, sputtering, charge exchange and energetic photochemical products. Stellar-wind interactions and photoionization supply particles with escape energies not represented by the local thermal tail. These mechanisms can act together rather than constituting four mutually exclusive evolutionary states.
Three physically distinct mechanisms are as follows.
Thermal-tail escape, a bulk hydrodynamic wind, and nonthermal particle energization are three distinct channels; a detected tail need not distinguish them alone. Jeans escape and hydrodynamic atmospheric escape are both thermal mechanisms in the broad sense, but have different distribution functions and dynamical assumptions.