For a parity-symmetric one-dimensional potential, the even and odd parity states diagonalize the One-dimensional S-matrix:
For a real potential, unitarity further gives at real positive energy.
For incidence from the left, normalize the asymptotic wavefunction by
For incidence from the right, define analogously with the directions reversed. Conservation of the probability current gives
Applying the same conserved sesquilinear current to the two scattering solutions gives
These are exactly the column orthonormality relations for the stated One-dimensional S-matrix, so is unitary.
For a wave incident from the left, define the reflection and transmission amplitudes by
Reflection invariance gives the same amplitudes for incidence from the right. If the incoming amplitudes from the left and right are ordered first, and the outgoing amplitudes toward the left and right second, the One-dimensional S-matrix is
For , the wavefunction is continuous and its derivative has the jump
The scattering ansatz gives
With
we obtain the scattering by a delta potential amplitudes
They satisfy
Therefore
so the scattering matrix is unitary.