For a reflection-invariant localized potential, order incoming amplitudes from the left and right and outgoing amplitudes toward the left and right. Then
where and are the reflection and transmission amplitudes. Probability-current conservation makes unitary for a real potential.
For a parity-symmetric one-dimensional potential, the even and odd parity states diagonalize the One-dimensional S-matrix:
For a real potential, unitarity further gives at real positive energy.
If the left and right travelling-wave coefficients are related by
then

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