Microscopic reversibility 2026-10-05
For an equilibrium process, a path and its physically time-reversed path have equal probability after including their equilibrium starting weights. Conditional on their endpoints, this means
This is the path version of detailed balance. A time-even order parameter is read backward without changing sign, while a transport flux changes sign. The Onsager--Machlup path probability implements this reversal in a coarse-grained stochastic description.
Model A fluctuation-dissipation relation Created 2026-09-28 Updated 2026-10-05
For nonconserved order-parameter dynamics, microscopic reversibility with equilibrium weight proportional to requires
Indeed the Onsager--Machlup path probability gives . Equating this to the detailed balance value proves the relation. The functional chain rule is understood with the same midpoint convention as the path action.
Write for the functional derivative of the action. Under time reversal in classical mechanics, changes sign whereas is even by assumption. Thus the forward and reversed Gaussian white noise histories associated with the same geometric path are
The Onsager--Machlup path probability therefore gives
Here the path probabilities are densities conditional on their respective initial states; they are not separately normalized bridges conditioned on both endpoints. The noise-to-path Jacobian determinant must be treated with a consistent discretization: it cancels when it is invariant under time reversal in classical mechanics. This is the usual additive-noise Langevin dynamics convention, including a constant-mass Underdamped Langevin dynamics or the time-reversal invariance of a path Jacobian in midpoint overdamped Langevin dynamics. A completely arbitrary velocity-dependent Lagrangian would require specifying that measure rather than deducing its cancellation solely from the parity of .
Write and . Eliminating the noise gives . The Onsager--Machlup path probability is therefore
These are conditional path densities given the corresponding starting configuration. For a time-even vector order parameter, reversal reads the configurations backward, changes to , and keeps unchanged on each corresponding configuration.
The two Gaussian white noise measures have the same normalization. With a common midpoint discretization, the noise-to-path Jacobian also agrees under reversal by time-reversal invariance of a path Jacobian. The common factor may include that path-dependent Jacobian; it need not be a universal constant. This makes the shared-factor assertion precise while leaving the requested ratio unaffected.
Put . For a specified forward trajectory, the equation of motion determines
whereas its time reverse requires
Assume the action is invariant under time-reversal symmetry, the position is even and velocity is odd under time reversal, and the trajectory-to-noise Jacobian is identical in the two directions. The Onsager--Machlup path probability is then
with replaced by for . Since
their ratio is
Path probability 2026-10-05
A path probability is a probability measure, or a density relative to a specified reference measure, on histories of a stochastic process. A formal Onsager--Machlup path probability must be interpreted with its discretization and initial-state conditioning specified; conditioning on both endpoints produces a separately normalized bridge measure.