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Difference-frequency generation produces a wave at the positive difference ${\omega }_i={\omega }_p-{\omega }_s$ of two incident angular frequencies, through a second-order nonlinear optical susceptibility. The product of two oscillating electric fields contains both sum and difference frequencies, and the corresponding polarization density drives the generated wave.

For plane waves in a uniform medium, coherent buildup is favored by ${\mathbf{k}}_p={\mathbf{k}}_s+{\mathbf{k}}_i$, the relevant phase matching condition. Two shorter-wavelength inputs can thereby generate longer-wavelength infrared radiation. Collecting the output after removing both incident frequencies distinguishes frequency generation from scattered pump light.^[ref]

An optical parametric amplifier transfers energy from a pump beam into a signal and an idler through nonlinear optics. For the common three-wave mixing process, their angular frequencies obey ${\omega }_p={\omega }_s+{\omega }_i$. A strong pump and a weaker signal enter a nonlinear medium; the signal grows and an idler is generated.

Efficient growth requires phase matching so that contributions generated along the medium reinforce. Changing crystal orientation or temperature can tune the matched frequencies. Measuring the signal with and without the pump tests amplification, while observing the corresponding idler checks the frequency-conversion mechanism. The pump supplies the extra energy; the process does not require a stored population inversion.^[ref]

Optical parametric chirped pulse amplification combines the stretch–amplify–compress sequence of chirped pulse amplification with an optical parametric amplifier. A stretched signal pulse overlaps a strong pump pulse in a nonlinear crystal. Three-wave mixing transfers pump energy into the signal and an idler; subsequent pulse compression brings the amplified signal's frequencies back together. The pump supplies the added energy, rather than a stored population inversion.^[ref]

A. Dubietis, G. Jonušauskas and A. Piskarskas reported chirped and stretched pulse parametric amplification in beta barium borate in 1992. Their paper establishes a concrete early implementation of the parametric route; its published title identifies the nonlinear crystal.^[ref]

For pump, signal and idler angular frequencies, the conversion obeysEfficient amplification also requires phase matching, so contributions generated along the crystal reinforce. For collinear propagation the corresponding wave-vector relation is $k_p=k_s+k_i$; a noncollinear geometry requires the vector relation. Crystal dispersion and the chosen geometry determine which signal bandwidth is efficiently amplified.

An original energy-accounting example uses a 515-nanometre pump and an 800-nanometre signal. Their vacuum wavelengths giveSuppose 40 percent of a 2-millijoule pump is converted into signal–idler pairs, with negligible seed energy and other losses in this chosen model. Each conversion divides photon energy according to frequency, so the added signal energy isThe idler receives the remaining 0.285 millijoule. Assigning all depleted pump energy to the signal would violate this accounting.

If a compressor transmits 80 percent of that signal energy into a 50-femtosecond Gaussian pulse, the surviving energy is 0.412 millijoule. The chirped pulse amplification energy budget givesThese are stipulated teaching values, not a reconstruction of the 1992 experiment. Stretching lowers peak power during amplification; it does not remove the need to manage pump intensity or optical damage.

A useful apparatus check varies pump–signal delay while recording signal and idler spectra and energies. This tests temporal overlap and the frequency-conversion relation. Measuring the compressed pulse separately checks whether amplified bandwidth and residual spectral phase support the claimed pulse duration. Gain alone does not demonstrate successful compression, and an energy measurement alone does not establish peak power.