Past exam of the chemistry A course of the University of Cambridge / 2025 / Paper 1 / A2 / b / Solution

Let $a={\varphi }_{1s}$ and $b={\varphi }_{2s}$ be orthonormal atomic orbitals. The normalized spatial factors areFor the singlet state, use the antisymmetric spin factorFor the three components of the triplet state, useEach total wavefunction obeys the Pauli principle. At coincident spatial coordinates,Consequently the triplet pair probability density vanishes at coincidence, even for its $M=0$ component. This zero is stronger than the trivial statement that any exact point has zero integrated probability in a continuum.