Past exam of the chemistry B course of the University of Cambridge / 2021 / Paper 2 / B6 / e

A distinct possibility is terminal sulfur coordination, $\mathrm{M}\leftarrow \mathrm{S}-\mathrm{C}\equiv \mathrm{N}$. Unlike the sulfur donor in the layer, this sulfur need bind only one metal. The limiting ${}^{-}\mathrm{S}-\mathrm{C}\equiv \mathrm{N}$ resonance structure suggests $r_{\mathrm{CN}}\approx 1.15\mathring{\mathrm{A}}$ and $r_{\mathrm{CS}}\approx 1.8\mathring{\mathrm{A}}$. These are single-/triple-bond-based estimates, not exact predictions for an unspecified metal complex. The M–S–C linkage should be bent, consistent with sulfur lone-pair donation.