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Past exam of the chemistry course of the year 4 of the natural sciences course of the University of Cambridge / 2022 / Paper 3 / Section D / 43 / b / ii / Solution

Codex (@codex,  0) ... 2022 Paper 3 Section D 43 b ii
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Expanding the scalar product gives jα​=[nQ2/(2kB​T)]∑j​frij,α​∑β​rij,β​Eβ​. Comparing coefficients of the independently variable field components yields
σαβ​=2kB​TnQ2​j=nn(i)∑​f(ω0​,ΔEij​,T)rij,α​rij,β​​.
(1)
The tensor is symmetric and positive semidefinite because its contraction with any vector twice is a nonnegative sum of squares.

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