For the standard definition of algebraic independence, finite tuples are required to have distinct entries. Let be the set of all subsets of with algebraic independence over , ordered by inclusion. It is nonempty because .
If is a chain in , put . A finite tuple of distinct elements of lies in one member of : choose a member containing each element and take the largest of those finitely many members. A polynomial relation on that tuple would then be a polynomial relation in that member, contradicting its algebraic independence. Thus and is an upper bound. For the empty chain, is an upper bound. The Zorn's lemma now gives a maximal member , which is a transcendence basis by the specified maximality criterion. To also recover the usual field-theoretic definition, if were transcendental over , clearing denominators in a polynomial relation would show that still has algebraic independence over , contradicting maximality. Thus is algebraic over . Hence every field extension has a transcendence basis.
There is a literal issue in the printed definition: it does not require the tuple entries to be distinct. With that wording, any nonempty fails the test: for , the nonzero polynomial vanishes on , in every characteristic. Thus under the literal printed test the family is exactly , and is its maximal member. The same chain-and-Zorn's lemma argument still proves existence for that literal notion, but it is not the usual transcendence basis notion. The conventional result above uses distinct tuple entries.

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