Thomson scattering generates linear Cosmic microwave background polarization when the incident radiation has a photon quadrupole. The cross-section prefers electric fields perpendicular to the scattering direction. Contributions from an isotropic field cancel, and a dipole alone does not supply the required spin-two angular pattern. Schematically the outgoing Stokes combination is proportional to
which selects the incident quadrupolar angular dependence. Tight coupling nearly isotropizes the radiation, making the quadrupole small; it develops when the photon mean free path becomes finite near decoupling. At leading tight-coupling order its size scales as .
The polarization is therefore weaker than the temperature anisotropy: a characteristic amplitude is of order a few percent to roughly ten percent of the temperature signal, or several microkelvin compared with temperature fluctuations of several tens of microkelvin on acoustic scales. This is an order-of-magnitude comparison, not a scale-independent ratio of every power-spectrum multipole.
The photon monopole follows the acoustic displacement, approximately ; the velocity sourcing the quadrupole follows . Hence polarization maxima occur near displacement zeros, between the main temperature peaks. In the leading coherent-oscillator approximation the shift is half the peak spacing, , although projection and gravitational driving modify exact locations. Scalar perturbations generate E-mode polarization at linear order, not B-mode polarization. Tensor perturbations and lensing can give B modes, and reionization generates an additional large-angle polarization feature.

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