Write , with and . Differentiating the Planck photon distribution givesDividing by proves the first-order thermal Sunyaev-Zeldovich effect:In the Rayleigh-Jeans law limit, and , so . In the Wien approximation, the prefactor approaches and the bracket approaches , so . The last limit is an asymptotic description of the first-order coefficient: a perturbative prediction at large still requires .
Hot electrons transfer energy to the cosmic microwave background, removing low-frequency photons and enhancing the high-frequency tail. The first-order distortion crosses zero where , at ; for today's CMB this is near . Photon conservation follows directly from the boundary termIn contrast, integration by parts gives , so radiation gains a fraction of its original energy. The thermal Sunyaev-Zeldovich effect is thus a spectral distortion, not simply a new blackbody temperature.
A galaxy cluster with bulk peculiar velocity along the line of sight additionally produces the kinetic Sunyaev-Zeldovich effect. Define for recession and . To first order in velocity and optical depth, : receding gas gives a decrement and approaching gas an increment. Its occupation number perturbation is , the spectrum of a small blackbody temperature change. It remains nonzero at the thermal null and therefore complicates measurements near that frequency.
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