A left-invariant vector field on a Lie group satisfies
or equivalently for every . For , define
This is smooth because multiplication is smooth and its differential depends smoothly on the base points. The identity gives , so is a left-invariant vector field. Conversely, left invariance forces any such field to have this form with . Evaluation at and the construction above are inverse linear maps. Hence
The Lie bracket of vector fields is their commutator as derivations on smooth functions: . It is another vector field because the cross terms cancel in the Leibniz rule for its action on a product. The bracket is preserved by a diffeomorphism: conjugating the derivation operators by pullback of a smooth function preserves their commutator. Therefore
for left-invariant . These fields are consequently closed under the bracket.
Transport the bracket to the tangent space by
Bilinearity and antisymmetry come from the commutator. The Jacobi identity follows by expanding the three nested commutators of derivation operators: their six terms cancel in pairs. Thus is a Lie algebra, and the displayed correspondence is a Lie algebra isomorphism onto the algebra of left-invariant vector fields.

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