Since the hom-sets in these categories are either empty or singleton, an adjunction is precisely the condition
The hom-set bijections are then the unique possible ones, and naturality is automatic. This is a Galois connection between the two posets.
Equivalently, the monotone functions satisfy the unit and counit inequalities and . The equivalence implies these by taking and . Conversely, if the inequalities hold, implies , while implies .

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