Use metric signature , as required by the sign of the scalar product in this question. For a massive particle, the four-momentum is
For a photon of positive frequency and direction , the Planck constant gives and
A future-pointing timelike four-vector has and in this signature. The ordinary Euclidean Cauchy-Schwarz inequality yields
This is stronger than the requested nonnegative inequality. For an electron and a positron of rest mass , their future-pointing timelike four-momenta have . Thus
which cannot equal the null norm of a single photon. Four-momentum conservation forbids spontaneous photon decay into an electron-positron pair in vacuum. An external body or field able to exchange momentum would be a different system.
For , take the initial electron direction as the longitudinal axis and put . Incoming four-momentum conservation gives
The transverse components must cancel. In the noncollinear case the two transverse directions are opposite, and . Hence the ratio of longitudinal momentum times to energy is
Writing and , the last ratio is . It also equals whenever that denominator is nonzero. Since , the angular relation for two-photon electron-positron annihilation is
The positive root follows from . For noncollinear emission the positive momentum-to-energy ratio ensures , and ensures the stated denominator is positive.
The printed quotient needs a qualification for exactly collinear photons. The allowed configuration , has positive frequencies
which obey both conservation equations, but the printed left side is . Thus the quotient holds for noncollinear angles, or as its appropriate noncollinear limit. The undivided identity
remains true in the collinear case, where both sides vanish. The limit similarly requires care because the initial direction is then undefined and the photons are antiparallel.

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