Let . The preceding invariant formula for the exterior derivative identifies the expression in the question with
Its vanishing for every pair of global vector fields is equivalent to : global fields with arbitrary prescribed tangent values are available by bump-function extension. Thus it is exactly the condition that be a closed differential one-form.
By definition, the first de Rham cohomology is closed one-forms modulo exact differential forms. The hypothesis makes every closed one-form exact. Hence gives a globally smooth function with , and
Conversely, if , then
by the definition of the Lie bracket of vector fields. Equivalently, . The bracket compatibility condition is necessary and, when , sufficient for a global potential. The potential is unique up to a constant on each connected component, since the difference of two potentials has zero differential.

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