Before decay, the nonrelativistic density redshifts as , while the photon density redshifts as . Therefore their ratio grows as . Let a minus sign denote the instant just before decay and defineUsing the assumed radiation domination law gives .
Across an instantaneous decay the scale factor does not change. Energy conservation and complete thermalization into a zero-chemical-potential photon bath giveSince blackbody radiation has , instantaneous photon heating by a decaying relic givesThe already decoupled Cosmic neutrino background is not heated. Dividing its unchanged temperature by the new photon temperature therefore yieldsThe relation written with is independent of the expansion approximation. Replacing it by the time ratio uses the radiation-dominated background assumed in the question; an appreciable matter contribution would require solving for that background instead. This photon entropy injection is not adiabatic, so the pre-decay photon entropy need not be conserved across the decay.
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