Blackbody radiation is a thermal equilibrium gas of photons. In units with , its energy density isand its isotropic radiation pressure is .
In a large periodic box of volume , one polarization has wavevector modes per unit . The two transverse photon polarizations therefore giveafter integration over directions.
For an equilibrium system with energy and no conserved particle number, exactness of the entropy differential obtained from givesIf and as , integration gives .
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