Write the perturbation as and use the same factor for all velocity and pressure amplitudes. At the upper interface, the linearized kinematic boundary condition, zero tangential traction, and normal-stress balance areThe first term in the normal stress is the linearization of the attractive disjoining pressure , while the second is the stabilizing capillary pressure. Symmetry about makes even and odd, and supplies the lower-interface conditions.
For a two-dimensional Fourier mode, the Papkovich–Neuber representation is equivalently expressed by the odd Biharmonic stream function for planar Stokes flowThe tangential-stress condition at , with , giveswhereas the kinematic condition gives . The associated normal traction isEquating this with the linearized interfacial traction yields the dispersion relationThis is the Van der Waals rupture instability of a viscous sheet.
For , the growth rate is positive, starts from as , and decreases to zero like as . For , it has the same long-wave limit, vanishes at , and is negative for : surface tension damps wavelengths shorter than the cutoff. Long waves feel the attractive interaction but require coherent flow over a large distance; at short wavelengths viscous resistance suppresses the clean-film instability, while capillarity adds direct decay. A finite film size, fluid inertia, surrounding-fluid stresses, gravity, surface viscosity, and failure of the continuum disjoining pressure law can shift the observable most unstable wavelength.
During a growing thin spot, interfacial flow stretches the surface and dilutes its surfactant, thereby increasing the local surface tension above . Adjacent less-stretched regions retain more surfactant and lower tension. The resulting surface-tension gradient pulls toward the thin spot and opposes the outward flow that drives thinning. This is surfactant stabilization of film rupture; in the strong limit the surfaces behave almost as immobile boundaries.
For strong surfactant and , instability requires . The Taylor expansionreduces the supplied relation toIt is maximal atThus the characteristic rupture time is . Surfactant greatly extends the life of a soap bubble while its film is moderately thick, but the growth-rate dependence predicts rapid final rupture after drainage has made the film sufficiently thin.
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