 Surface tension

Surface tension $\gamma$ is the tensile force per unit length across a line drawn in a liquid interface. For a clean interface with isotropy, it has the same value in every tangential direction: each side pulls the other along the surface, perpendicular to the line. A straight segment of length $\ell$ therefore transmits a force of magnitude $\gamma \ell$ from one interface. Here we assume constant $\gamma >0$, with fixed temperature and composition. The same coefficient measures the reversible work required to create surface area:The equality of units follows from $1\mathrm{J}=1\mathrm{N}\mathrm{m}$; the equality of the mechanical coefficients follows from the moving-rim argument below. ^{[ref] [ref]}

For a concrete example, take an ideal flat soap film spanning a rectangular wire frame with a straight sliding rim of length $\ell$. Pull the rim outwards in the plane of the film, perpendicular to the rim. Each of the film's two liquid–gas interfaces pulls the rim back towards the film with force $\gamma \ell$, so the outward holding force is $F=2\gamma \ell$. The two faces are two interfaces, each with its own surface tension. With the assumed toy value $\gamma =0.072\mathrm{N}{\mathrm{m}}^{-1}$ and $\ell =20\mathrm{mm}=0.020\mathrm{m}$, the required force is $2.88\mathrm{mN}$; one interface would contribute $1.44\mathrm{mN}$. This value of $\gamma$ is a stipulated model parameter, rather than a measured value for a particular soap solution.

Why does an interface resist being enlarged? Its molecules have a different environment from those in the bulk liquid; changing that environment has an energy cost. In the constant-surface tension model, reducing surface area lowers surface energy. This connects an easily measured rim force to the shape of a droplet, the Young–Laplace equation for its pressure, and the restoring mechanism of capillary waves. It is useful because one coefficient links forces, energy and geometry. ^[ref]

The moving-rim argument also explains the factor of two without memorizing a special formula. An outward displacement $dx$ creates surface area $\ell dx$ on each face, hence $d{A}_{\mathrm{total}}=2\ell dx$. Slow pulling without viscous dissipation requires work $Fdx=\gamma d{A}_{\mathrm{total}}$, giving $F=2\gamma \ell$. For one interface, the same argument gives $F=\gamma \ell$. A surface tension gradient instead produces Marangoni stress; the constant-$\gamma$ assumption excludes that additional effect.

Surface tension is a physical property of liquids that arises from the cohesive forces between liquid molecules. It is defined as the energy required to increase the surface area of the liquid by a unit area. At the molecular level, surface tension occurs because molecules at the surface of a liquid experience a net inward force: they are attracted more strongly to the molecules beside and below them than to the air above. This results in a "skin-like" effect on the surface of the liquid.