For and electromagnetism neglected, the classical flavour symmetry is
up to finite quotients. The chiral anomaly breaks quantum mechanically, while remains. The quark condensate
spontaneously breaks
Small quark masses and electromagnetism explicitly break parts of this approximate symmetry.
Introduce the linear sigma model field
A suitable renormalizable potential is
with a small symmetry-breaking source proportional to the quark-mass matrix when desired. A vacuum is fixed precisely by , so the unbroken group is the diagonal isospin . The three broken axial generators produce the pion triplet , which become pseudo-Goldstone bosons when are restored.
At energies well below , collect the pion fields into
The leading chiral perturbation theory Lagrangian is
where is treated as a symmetry-breaking spurion. The derivative and quark-mass expansion organizes the omitted terms.
Exact isospin symmetry would make the proton and neutron degenerate. Their observed mass difference is generated by explicit isospin breaking from together with electromagnetic effects. The approximate symmetry explains why the splitting is small compared with the nucleon mass, while chiral perturbation theory parametrizes it through symmetry-breaking operators and low-energy constants; symmetry alone does not predict its numerical value.

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