Separating variables gives
Therefore
For , define the strong-coupling scale
Then
It decreases logarithmically toward zero in the ultraviolet and grows toward the infrared, becoming nonperturbative when approaches .
For , the theory is asymptotically free: it is weakly coupled at high energies and strongly coupled in the infrared. For , the coupling decreases toward the infrared but grows toward a finite ultraviolet Landau pole; such a theory is infrared free and requires an ultraviolet completion before that pole.
Let
Running each coupling down from the common value gives
Subtracting the equations determines , and eliminating it from the difference gives
which is the claimed gauge coupling unification relation.
Below the strange-quark threshold, the gauge-field and two-flavour quark terms are
where
This is the low-energy Quantum chromodynamics plus electromagnetism Lagrangian for the light flavours.
Every renormalizable gauge-invariant term contains equal numbers of quark and antiquark fields. The common phase symmetry
is therefore automatic rather than imposed in constructing the Lagrangian. Its conserved charge is baryon number, making an accidental symmetry of the renormalizable low-energy theory.
For and electromagnetism neglected, the classical flavour symmetry is
up to finite quotients. The chiral anomaly breaks quantum mechanically, while remains. The quark condensate
spontaneously breaks
Small quark masses and electromagnetism explicitly break parts of this approximate symmetry.
Introduce the linear sigma model field
A suitable renormalizable potential is
with a small symmetry-breaking source proportional to the quark-mass matrix when desired. A vacuum is fixed precisely by , so the unbroken group is the diagonal isospin . The three broken axial generators produce the pion triplet , which become pseudo-Goldstone bosons when are restored.
At energies well below , collect the pion fields into
The leading chiral perturbation theory Lagrangian is
where is treated as a symmetry-breaking spurion. The derivative and quark-mass expansion organizes the omitted terms.
Exact isospin symmetry would make the proton and neutron degenerate. Their observed mass difference is generated by explicit isospin breaking from together with electromagnetic effects. The approximate symmetry explains why the splitting is small compared with the nucleon mass, while chiral perturbation theory parametrizes it through symmetry-breaking operators and low-energy constants; symmetry alone does not predict its numerical value.
The strange quark is light enough compared with typical hadronic scales to permit an approximate
chiral expansion. It adds kaons and the eta to the pseudo-Goldstone multiplet, although convergence is poorer because is substantially larger than .
The charm quark is too heavy for the same light-flavour chiral expansion. At low energies it is integrated out; processes containing charm are instead treated using heavy-quark expansions or other effective theories. Thus the analysis extends approximately to , but not to as another pseudo-Goldstone-producing light flavour.

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