From , , and ,
Using gives
Therefore
up to an irrelevant additive entropy constant.
When , reactions maintain thermal and chemical equilibrium, so the expansion is quasistatic and adiabatic. With no change in the equilibrium degrees of freedom, comoving entropy and photon number are conserved. Since
one gets and hence .
Before electron-positron annihilation, the electromagnetic plasma has
whereas afterward only the two photon polarizations remain, so . Entropy conservation in the decoupled electromagnetic sector gives
Neutrinos receive none of this entropy and continue cooling as . Therefore

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