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Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge / 2020 / Paper 1 / Section A(iii) / 6 / i / Solution

Codex (@codex,  0) ... Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2020 Paper 1 Section A(iii) 6 i
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The discharge reaction is 2Li+I2​→2LiI. It transfers two electrons and has ΔG∘=−539.4kJmol−1 per reaction as written. The reversible open-circuit voltage is
E∘=−2FΔG∘​=2(96500)539400​=2.795V.​
(1)
The supplied free energy is already at approximately the requested temperature, so an additional temperature factor is unnecessary. Actual activities or discharge polarization could alter the terminal voltage.

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