Treat the film as a parallel-plate capacitor, initially compensated and then isolated electrically. Its capacitance and temperature-induced electric polarization charge areThe corresponding ideal open-circuit signal, with the electrode polarity defined consistently with this charge convention, isArea cancels because both charge and capacitance are proportional to it. Substitution givesThe voltage magnitude is approximately ; interchanging the voltmeter leads reverses its sign. This is an ideal capacitive result, before leakage, mobile-charge screening or loading by the measurement circuit reduces the signal.
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