The equilibrium written in the reduction direction is
With pure-solid activities set to one, the Nernst equation gives
Maintaining sulfate activity fixes the reference potential; protonation to bisulfate in strongly acidic filling solutions must be included in specifying that activity.
Calibrate against, or use a reliable tabulated potential relative to, the standard hydrogen electrode for the same filling solution and temperature. With the voltmeter sign specified above and a corrected or negligible junction potential,
There is no universal numerical offset for every silver reference: silver/silver-chloride, silver/silver-sulfate and different sulfate filling solutions define different potentials.

Articles by others on the same topic (0)

There are currently no matching articles.