Insert position resolutions between short-time evolution factors for . Integrating the momenta gives the path integral, with real-time slice factor and weight . A real classical trajectory cannot pass through a barrier with insufficient energy, but the path integral includes nonclassical paths.
Continue , with s physical imaginary time. The damped kernel isThe Euclidean action saddle obeys : motion in the inverted potential. For degenerate minima at , subtract their common potential energy. A trajectory joining them with zero Euclidean energy satisfiesIt is an instanton; reversing its direction gives an anti-instanton. Thus a crossing amplitude is nonperturbative, proportional to . For the representative quartic well , direct integration givesThe arbitrary center is an instanton translation zero mode. Expanding gives a Gaussian path integral involving . Treating the zero mode as a collective coordinate rather than a zero Gaussian denominator produces the instanton fluctuation prefactorCommon endpoint regularization defines the functional determinant ratio; K and kappa have inverse-time units. The prime removes only the zero eigenvalue, while integrating the center supplies the total available time. Large and justify a dilute instanton gas.
Multiple crossings alternate direction. Integrating n ordered centers gives . Return paths contain even n, and transfer paths contain odd n, so their common local-well factor multiplies and respectively. The two lowest levels are consequentlyThe lower state is the even combination of the two localized states. Local anharmonic corrections modify and higher semiclassical corrections modify K. The thermal trace as a closed Euclidean path integral gives when higher local levels are negligible. This describes coherent level splitting in a stable well, not irreversible decay.
For a scattering barrier at energy E, the leading WKB tunnelling exponent gives an amplitude and a transmission probability with twice that exponent. Endpoint matching fixes prefactors. Metastable escape instead uses a Euclidean bounce, with a negative fluctuation mode and a decay rate. Neither its negative mode nor the probability/amplitude factor should be transplanted into the stable double-well splitting. [ref]
Gauge Theory by David Tong. Chapter2, §§2.3.2–2.3.3, printedpp.56–60: quantum-mechanical tunnelling, fluctuation determinants and repeated instanton events
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