Postnikov invariant ($k_n$)

The $n$th Postnikov invariant is the cohomology class $k_n\in H^{n+1}(P_{n-1}X;{\pi }_{n}X)$ whose representing map has homotopy fibre $P_{n}X$. It specifies how the new homotopy group is attached to the previous stage. A zero invariant gives the product $P_{n}X\simeq P_{n-1}X\times K({\pi }_{n}X,n)$. Merely tensoring homotopy groups with $\mathbb{Q}$ does not describe rationalization of a topological space unless these classes are also transported.