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Over $\mathbb{C}$, the symplectic Lie algebra on a four-dimensional symplectic vector space acts faithfully on its five-dimensional primitive exterior square, preserving its symmetric bilinear form. Faithfulness follows because an operator killing all wedges $e_i\wedge e_j$ has all off-diagonal coefficients zero and satisfies $A_{ii}+A_{jj}=0$ for every pair, hence is zero. The source and target Lie algebras both have dimension ten, so this faithful map is an isomorphism to the Special orthogonal Lie algebra ${\mathfrak{so}}_5$.

Let $U$ be a four-dimensional symplectic vector space. The symplectic contraction of an exterior square splits ${\Lambda }^{2}U$ into its five-dimensional primitive exterior square $W$ and the invariant line spanned by the inverse symplectic bivector $\Omega$. Choose $\mathrm{vol}=\Omega \wedge \Omega /2$. Exterior multiplication defines a symmetric bilinear form on ${\Lambda }^{2}U$ by $\xi \wedge \eta =B(\xi ,\eta )\mathrm{vol}$; it is symmetric because both degrees are two. In a symplectic basis, $\Omega \wedge \Omega =2\mathrm{vol}\ne 0$, and $W={\Omega }^{\perp }$, so the restriction to $W$ is nondegenerate.

The symplectic Lie algebra ${\mathfrak{sp}}_4$ preserves this form, giving a homomorphism ${\mathfrak{sp}}_4\to \mathfrak{so}(W)$. It is injective: an element acting trivially on $W$ also acts trivially on $\Omega$, hence on all of ${\Lambda }^{2}U$. In a four-vector basis, the identities $A{e}_i\wedge e_j+e_i\wedge A{e}_j=0$ first force every off-diagonal coefficient of $A$ to vanish, then force $A_{ii}+A_{jj}=0$ for every pair. Over $\mathbb{C}$ these equalities imply $A=0$.

Both Lie algebras have dimension ten: $\dim {\mathfrak{sp}}_4=4\cdot 5/2$ and $\dim {\mathfrak{so}}_5=5\cdot 4/2$. The injective map is therefore an isomorphism, proving the exceptional isomorphism between sp4 and so5: