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Work in the homotopy category of simply connected CW complexes. This is one of the permitted assumptions on the fundamental group; it makes every coefficient system below untwisted. A rational space is a simply connected space whose homotopy groups are vector spaces over $\mathbb{Q}$. A rationalization of a topological space is a map $r:X\to X_{\mathbb{Q}}$ to such a space which inducesIts purpose includes a universal mapping property, which will be described after the construction.

An Eilenberg–MacLane space $K(A,n)$ has exactly one nonzero homotopy group, ${\pi }_n=A$, where $A$ is abelian when $n\ge 2$. The representability theorem says $[B,K(A,n)]\cong H^n(B;A)$, naturally in $B$ and $A$. More generally, a principal fibration is a homotopy pullback of a path-space fibration $PC\to C$ along a map from its base to $C$; the fibre $\Omega C$ acts on the fibre paths by concatenation. For the Postnikov tower construction take $C=K(A,n+1)$. A principal Eilenberg–MacLane fibration with fibre $K(A,n)$ is the homotopy pullback of the path fibration of $K(A,n+1)$. Equivalently, its total space is the homotopy fibre of a map $k:B\to K(A,n+1)$. It is classified by the cohomology class $[k]\in H^{n+1}(B;A)$; there is no nontrivial action of the base fundamental group on the fibre coefficients in this principal description.

The Postnikov tower theorem supplies spaces $P_{n}X$ and compatible mapswith ${\pi }_i(P_{n}X)={\pi }_i(X)$ for $i\le n$ and zero for $i>n$. For a simply connected $X$, the fibre of $P_{n}X\to P_{n-1}X$ is $K({\pi }_{n}X,n)$, and the fibration is principal. Its Postnikov invariant isrepresented by $P_{n-1}X\to K({\pi }_{n}X,n+1)$, whose homotopy fibre is $P_{n}X$. Thus the homotopy groups alone are not the tower data: the classes $k_n$ specify how each new group is attached. For instance a zero class gives a product with $K({\pi }_{n}X,n)$.

State also the standard rational comparison results used in constructing the tower: $K(A,n)\to K(A\otimes \mathbb{Q},n)$ is a rational homology equivalence; a map between simply connected spaces is a rational homology equivalence if and only if it induces isomorphisms on all rational homotopy groups; and a rational homology equivalence induces isomorphisms in cohomology with any constant rational vector-space coefficients. The last assertion uses the universal coefficient theorem over the field $\mathbb{Q}$. These results are used here without proof, as allowed for this essay.

Construct rational stages inductively, with $P_1^{\mathbb{Q}}=\ast$. Suppose $r_{n-1}:P_{n-1}X\to P_{n-1}^{\mathbb{Q}}$ has already been constructed and is a rational homology equivalence. Put $V_n={\pi }_{n}X\otimes \mathbb{Q}$ and change coefficients in $k_n$ to obtain ${\overline{k}}_n\in H^{n+1}(P_{n-1}X;V_n)$. The comparison result gives an isomorphismLet $k_n^{\mathbb{Q}}$ be its unique inverse image and defineEquality of the pulled-back classes gives a homotopy-commuting square of classifying maps, and hence a map $r_n:P_{n}X\to P_n^{\mathbb{Q}}$ over $r_{n-1}$. On the fibre it is the map induced by ${\pi }_{n}X\to V_n$. The homotopy exact sequences therefore show that $r_n$ tensors all homotopy groups through degree $n$ with $\mathbb{Q}$, while the higher groups of both stages vanish. The rational comparison theorem makes $r_n$ a rational homology equivalence, allowing the induction to continue.

Take the homotopy inverse limit of the rational tower:The convergence theorem for a Postnikov tower gives $X\simeq {\mathrm{holim}}_n{P}_{n}X$ and the compatible stage maps induce $r:X\to X_{\mathbb{Q}}$. To see what convergence says here, fix a homotopy degree $i$. From stage $n\ge i$ onwards the group and its transition maps are constant; the inverse-limit group is ${\pi }_{i}X\otimes \mathbb{Q}$ and the associated derived-limit obstruction is zero. Thus this construction has exactly the claimed rational homotopy groups. Taking a homotopy limit, rather than an arbitrary set-theoretic inverse limit, is part of the construction.

The rational localization theorem says that this map has the universal propertyIn other words every map from $X$ to a rational space factors through $r$, and the factorization is unique up to homotopy. This concerns homotopy classes, not strict uniqueness of point-set maps. The theorem can be formulated as localization of the simply connected homotopy category at rational homotopy equivalences; rational spaces are its local objects. It also implies uniqueness of rationalization of a topological space: apply the property to two candidate rational spaces to obtain inverse equivalences under $X$. In particular the construction forgets torsion in homotopy while retaining precisely the information needed for maps to rational targets.

The same theory extends to nilpotent spaces, where the fundamental group is nilpotent and its action on higher homotopy groups is nilpotent. That version requires localization of the fundamental group and compatible treatment of its coefficient action. The simply connected assumption chosen here avoids those additional issues and supplies the full construction and mapping property requested.

A Postnikov tower of a connected CW complex $X$ consists of spaces $P_{n}X$ with ${\pi }_i(P_{n}X)={\pi }_i(X)$ for $i\le n$ and zero for $i>n$, together with compatible maps $X\to P_{n}X\to P_{n-1}X$. For simply connected $X$, each stage is a principal Eilenberg–MacLane fibration with fibre $K({\pi }_{n}X,n)$, classified by a Postnikov invariant. The canonical map $X\to {\mathrm{holim}}_n{P}_{n}X$ is a weak equivalence: in each homotopy degree the tower is eventually constant, so the derived inverse-limit obstruction vanishes.

A principal fibration, in the homotopy-theoretic sense, is a homotopy pullback of a path-space fibration $PC\to C$ along a map $k:B\to C$. Its fibre is $\Omega C$ and acts on the fibre paths by concatenation, freely and transitively up to the relevant homotopies. Principal bundles for a topological group give this construction through its classifying space. When $C=K(A,n+1)$, the fibre is $K(A,n)$ and the principal fibration is classified by $H^{n+1}(B;A)$, yielding a principal Eilenberg–MacLane fibration.