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In a unital C-star algebra $A$, an element is Hermitian when $x=x^{\ast }$, unitary when $x^{\ast }x=x{x}^{\ast }=1$, and normal when $x^{\ast }x=x{x}^{\ast }$. It is a Positive element of a C-star algebra when $x=y^{\ast }y$ for some $y$, equivalently when it is Hermitian and its spectrum lies in $[0,\infty )$.

Suppose first that $\Vert \tau \Vert =\tau (1)$, and normalize so that both equal one. If $x=x^{\ast }$, the C-star identity givesWriting $\tau (x)=a+ib$, we obtainfor every real $t$, which forces $b=0$. Decomposing an arbitrary $x$ into its Hermitian real and imaginary parts now gives

Let $x=x^{\ast }$. Every character of an algebra on the commutative unital Banach algebra generated by $x$ has norm and value at one equal to one, so the preceding argument makes its value on $x$ real. The character description of the spectrum of an element therefore gives $\sigma (x)\subset \mathbb{R}$. Iterating the C-star identity,so $\Vert x\Vert =r(x)$. If $c=\Vert x\Vert$, then $x+c1$ has nonnegative spectrum and is positive, as is $c1$; henceis a difference of positive elements.

If $0\le x$ and $\Vert x\Vert \le 1$, then spectral translation givesThus $1-x$ is positive and, by the norm--spectral-radius equality for Hermitian elements, $\Vert 1-x\Vert \le 1$.

Return to a norm-one $\tau$ with $\tau (1)=1$. For $0\le x\le 1$, the preceding paragraph and reality on Hermitian elements giveScaling proves that $\tau$ is a positive functional on a C-star algebra. Every character has norm and value at one equal to one, so every character is positive. On $C[0,1]$, the functionalis positive but is not multiplicative, and hence is not a character.

Conversely, let $\tau$ be positive. Writing a Hermitian element as a difference of positive elements shows that $\tau$ is real on Hermitian elements. Positivity offor every $\lambda \in \mathbb{C}$ says that the associated quadratic polynomial is nonnegative. Minimizing it in $\lambda$ gives the Cauchy--Schwarz inequalityTaking $y=1$ yields $|\tau (x){|}^2\le \tau (x^{\ast }x)\tau (1)$. Since $0\le x^{\ast }x\le \Vert x{\Vert }^{2}1$, positivity givesTogether with $\tau (1)\le \Vert \tau \Vert$, this proves $\Vert \tau \Vert =\tau (1)$.

Convex combinations preserve positivity and value one at the identity, so the state space $S(A)$ is convex. If $x$ is normal, the unital C-star subalgebra $C^{\ast }(1,x)$ is commutative and its Gelfand transform identifies it with $C(\sigma (x))$. Choose $\lambda \in \sigma (x)$ with $|\lambda |=\Vert x\Vert$. Evaluation at $\lambda$ is a state taking $x$ to $\lambda$. Its norm-preserving Hahn--Banach extension to $A$ still takes $1$ to one, so the norm criterion makes the extension a state $\tau$ satisfying $|\tau (x)|=\Vert x\Vert$.

The state space is nonempty, convex, and weak-star compact by the Banach-Alaoglu theorem. The Krein-Milman theorem gives an extreme point, so a pure state on a C-star algebra exists. For positive $x$, the preceding norm-attainment result makesa nonempty weak-star compact convex set. It is a face: if a convex combination has the maximal possible value on $x$, each summand does. An extreme point of $F$ exists by Krein--Milman and, because $F$ is a face, is extreme in $S(A)$. It is the required pure state.

A pure state on a C-star algebra is an extreme point of its state space. For a nonzero unital C-star algebra, the state space is a nonempty compact convex set in the weak-star topology, so the Krein-Milman theorem guarantees pure states.

Every Positive element of a C-star algebra $a$ attains its norm at a pure state. Indeed, states satisfying $f(a)=\Vert a\Vert$ form a nonempty compact face of a convex set: the maximum property forces each term of any nontrivial convex decomposition to attain the same maximum. An extreme point of this face is an extreme point of the whole state space. The argument uses the unital compactness statement, rather than asserting compactness for a general nonunital algebra.