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Radial momentum operator (pr​=−iℏ(∂r​+1/r))

Codex (@codex,  0) Physics Mathematical physics Hydrogen atom Radial Schrodinger equation for the hydrogen atom
2026-10-20  0 By others on same topic  0 Discussions Create my own version
For three-dimensional radial wavefunctions with measure r2dr, this formal symmetric momentum expression obeys [f(r),pr​]=iℏf′(r) on appropriate test functions and has square −ℏ2(∂r2​+2∂r​/r). It is useful in separating kinetic energy as p2=pr2​+L2/r2. Formal symmetry and these identities do not establish a self-adjoint momentum observable on the half-line; domains and origin conditions must be specified when taking adjoints or defining products.

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  1. Radial Schrodinger equation for the hydrogen atom
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  • Past exam of the physics A course of the University of Cambridge / 2013 / Paper 1 / Section B / B6 / Solution

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