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Sunlight is approximately unpolarized before its interaction with the environment. For Rayleigh scattering by small isotropic scatterers, the induced electric dipoles radiate only their components transverse to the viewing direction. For unpolarized incident light scattered through angle $\chi$, the perpendicular and parallel intensities are proportional to 1 and ${\cos }^2\chi$. The degree of linear polarization is thereforeAt $90^{\circ }$ single scattering is fully linearly polarized perpendicular to the scattering plane. This explains the polarized sky away from the Sun; multiple scattering and aerosols reduce the ideal contrast.

Reflection at a dielectric surface treats the two linear polarizations differently. At Brewster incidence, $\tan {\theta }_B=n_2/n_1$, the reflected p component vanishes for ideal transparent nonmagnetic media. The remaining reflected glare is s polarized, perpendicular to the incidence plane, approximately horizontal for a horizontal water surface. Away from this angle the reflection is generally partially polarized. The transmitted beam also has unequal s/p transmission.

Refraction and internal reflection in water droplets likewise have polarization-dependent Fresnel coefficients, producing strong linear polarization in rainbow light. These are generic scattering and boundary-condition mechanisms; no biological detection mechanism is required.

Both Thomson scattering and Rayleigh scattering can be understood as radiation from a dipole driven by the incident electric field. Their different frequency dependences come from the response of a free charge compared with a bound charge.

For a free particle of charge $q$ and mass $m$, a harmonic field gives $m\ddot{\mathbf{x}}=q\mathbf{E}$, hence $\mathbf{p}=q\mathbf{x}=-q^2\mathbf{E}/(m{\omega }^2)$. The radiated field contains two time derivatives of $\mathbf{p}$, cancelling the response's ${\omega }^{-2}$. The Thomson cross section is consequently independent of frequency in the classical low-recoil regime:For incident linear polarization with unit polarization $\mathbf{ϵ}$, summing over outgoing polarizations gives $d\sigma /d\Omega =r_q^2[1-|\hat{\mathbf{n}}\cdot \mathbf{ϵ}{|}^2]$. Radiation vanishes along the acceleration and is strongest perpendicular to it. Averaging an incident unpolarized light beam giveswhere $\Theta$ is the scattering angle. Scattering through $90^{\circ }$ is fully linearly polarized perpendicular to the scattering plane for this ideal isotropic dipole model. The electron case dominates over equally charged heavier particles because the cross section scales as $m^{-2}$. recoil corrections become necessary when photon energy is no longer small compared with $m{c}^2$.

For a bound charge with natural frequency ${\omega }_0$ and damping rate ${\gamma }_d$,Far below resonance, ${\alpha }_{\mathrm{e}}$ is approximately constant, soThis is Rayleigh scattering. It requires a scatterer small compared with the wavelength and, for the simple expression, an isotropic linear dipole response. Atoms, molecules and small dielectric particles provide examples. The stronger scattering of shorter visible wavelengths explains blue skylight; absorption and the nonuniform solar spectrum prevent treating that simple scaling as a complete color calculation.^[ref]

For isotropic electric scatterers the normalized angular and polarization patterns are the same as in Thomson scattering. The frequency scaling distinguishes their limits: a free charge has a displacement proportional to ${\omega }^{-2}$, whereas a tightly bound charge has an approximately frequency-independent displacement. Near resonance, far outside the small-particle limit, or with anisotropic polarizability, the simple Rayleigh formula must be modified. In particular, the electric-only pattern must not silently be applied to a perfectly conducting sphere whose magnetic dipole response is also retained.

A scattering measurement should subtract stray-light and detector backgrounds, control scatterer density and optical thickness, and calibrate detector response and incident power when comparing wavelengths. A polarization analyzer at $90^{\circ }$ tests the dipole pattern; multiple scattering or unresolved nonisotropic contributions can reduce its polarization.

In ideal single Rayleigh scattering of unpolarized incident light by an isotropic small scatterer, observed intensities perpendicular and parallel to the scattering plane are proportional to 1 and ${\cos }^2\chi$. Their normalized difference is $\mathcal{P}={\sin }^2\chi /(1+{\cos }^2\chi )$. At a right-angle scattering geometry the output is fully linear and perpendicular to that plane. Multiple scattering, large particles and anisotropic scatterers change this ideal sky-polarization law.