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Emissivity compares thermal emission from a surface with emission from an ideal blackbody at the same absolute temperature, using the same wavelength and angular averaging convention. For ordinary passive surfaces in the far field at local thermal equilibrium, the ratio lies between zero and one. A blackbody has emissivity one. Unless a spectral or directional qualification is given, the $ϵ$ in $M=ϵ\sigma T^4$ is total hemispherical emissivity: a ratio of emitted radiant exitances, not of all outgoing radiant flux including reflected radiation.^[ref]

Emissivity belongs to a specified surface state, not just a bulk material name. Coating, oxidation and surface finish can change it; wavelength, viewing direction and temperature also matter. A surface that looks white in visible light need not have low infrared emissivity. This distinction is useful when choosing a radiator coating or interpreting a radiation-based temperature measurement: a narrow-band detector needs the appropriate spectral emissivity, and its signal can include reflected surrounding radiation. The grey body and diffuse thermal emitter assumptions are separate simplifications, addressing wavelength and direction respectively.

A grey body has spectral emissivity independent of wavelength over the range in which the approximation is used. Under Kirchhoff's law of thermal radiation, the corresponding radiometric absorptance is also wavelength-independent. This allows the same factor to weight emission at $T$ and black-enclosure irradiation at a different $T_s$ in net radiative heat exchange. The factor can still depend on temperature; treating it as constant over a cooling curve is an additional assumption. Wavelength independence alone does not imply direction independence.^[ref]

Spectral emissivity compares emission with an ideal blackbody at the same temperature at a specified wavelength, or frequency under a consistently transformed convention. A hemispherical spectral emissivity uses spectral radiant exitance; a directional spectral emissivity uses spectral radiance. Always state which angular convention applies. A wavelength-selective coating can emit strongly in one band while emitting weakly elsewhere, so one band measurement does not determine total hemispherical emissivity.

Total hemispherical emissivity integrates over all emitted wavelengths and the outward hemisphere. If ${ϵ}_{\lambda ,\Omega }$ is spectral emissivity resolved by direction, and $B_{\lambda }(T)$ is blackbody spectral radiance from Planck's law, thenIt is a weighted average, not an unweighted mean of surface properties. Even if the wavelength-resolved material response stays unchanged, the Planck's law weighting changes with temperature, so the total ratio can change. Likewise, total radiometric absorptance averaged over radiation from hotter surroundings generally differs from this emission-weighted ratio. Kirchhoff's law of thermal radiation equates matched spectral and directional quantities; it does not equate arbitrary broadband averages.