A substitution reaction replaces an atom or group in a molecular entity with another. The replacement can occur through one elementary step or several; the definition specifies the net chemical change rather than a unique mechanism.[ref]
For example, in , a nucleophile replaces a leaving group. Concerted displacement and a pathway through a carbocation can have different concentration dependences and stereochemical outcomes even when the written products match. The reacting functional group, solvent and competing elimination reactions help determine which pathway is observed.

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