Only states within an energy shell of width roughly around appreciably change occupation at low temperature. There are roughly such states and each excitation costs energy of order . Thus , giving . This is the thermal-shell estimate of electronic heat capacity; filled states far below are blocked by the Pauli exclusion principle. A smooth DOS and fixed particle number give the more precise Sommerfeld result to leading order.
Only a shell of energy width of order near the Fermi energy can change occupation: much lower states are blocked by the Pauli exclusion principle. The thermal-shell estimate of electronic heat capacity countsTo recover the rough coefficient requested in the paper, assign each of these active particles an excitation energy of order . ThenThe differentiation matters: the active shell itself widens as temperature rises. This argument explains the small linear-in- electronic heat capacity; its shell width and average excitation energy are heuristic, so it does not establish a precise numerical prefactor.
A controlled calculation from the Fermi-Dirac distribution gives a nearby but different result. At fixed particle number, the Sommerfeld expansion yieldsThus is a rough estimate of the exact free-electron coefficient , not an exact consequence of the stated density of states. Both require .