Tree scattering in Yukawa theory (${\mathcal{L}}_{\mathrm{int}}=-g\bar{\psi }\varphi \psi$)

For a real scalar coupled through $-g\bar{\psi }\varphi \psi$, the scalar-fermion Feynman vertex is $-ig$. Two-fermion scattering has scalar exchange in the $t$ and $u$ channels with a relative minus from exchanging identical external fermions. Fermion-antifermion scattering has $t$ exchange and $s$ annihilation, again with a relative fermionic minus for a fixed state ordering. Fermion-scalar scattering has the two orderings along one open fermion line, using internal momenta $p_1+p_2$ and $p_1-p_4$; these have the same sign. The Mandelstam variables specify the propagator denominators.