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At tree level this QED process has two internal muon exchange diagrams, differing by the order of the two outgoing photon vertices. Their propagator momenta are $p_1-k_1$ and $p_1-k_2$ for incoming muon momentum $p_1$. The amplitude begins at order $e^2$ and obeys the two-photon fermion Ward identity. Identical final photons require the usual factorial correction when integration over the full final-state Lorentz-invariant phase space would otherwise count them twice.

Take the muon mass to be $m_{\mu }$, and use the quantum electrodynamics convention ${\mathcal{L}}_{\mathrm{int}}=-e\bar{\psi }{\gamma }^{\mu }\psi A_{\mu }$ with $e>0$. Let $p_1,p_2$ be the incoming muon and antimuon momenta and $k_1,k_2$ the outgoing photon momenta, so $p_1+p_2=k_1+k_2$. External particles are on shell: $p_1^2=p_2^2=m_{\mu }^2$ and $k_1^2=k_2^2=0$. The two tree-level Feynman diagrams are the two orders in which the photon legs attach to the muon line. There is no three-photon QED vertex, and therefore no single-photon annihilation diagram into two photons at this order.

The QED Feynman rules needed here are the vertex $-ie{\gamma }^{\mu }$, the Dirac propagatoran incoming muon spinor $u(p_1)$, an incoming antimuon adjoint $\bar{v}(p_2)$, and an outgoing photon polarization ${ϵ}_{\mu }^{\ast }(k)$. At a vertex enforce four-momentum conservation. Spinor products are ordered along the fermion line; exchanging the external photons introduces no relative minus sign. Define $R(q)=(/q+m_{\mu })/(q^2-m_{\mu }^2+i0)$ and $/ϵ={\gamma }^{\mu }{ϵ}_{\mu }$.

With the convention that a diagram contributes $i\mathcal{M}$, the two muon-antimuon annihilation amplitudes areTheir denominators are respectively $t-m_{\mu }^2+i0$ and $u-m_{\mu }^2+i0$, where $t=(p_1-k_1{)}^2$, $u=(p_1-k_2{)}^2$. A different consistent overall amplitude-phase convention has no physical effect.

A physical photon polarization vector obeys $k\cdot ϵ=0$, and represents an equivalence class $ϵ\sim ϵ+\alpha k$. For a real null momentum, adding $\alpha k$ preserves transversality. One can additionally choose transverse spatial vectors with ${ϵ}^0=0$ and ${ϵ}^{\ast }\cdot ϵ=-1$; there are two independent physical polarizations. The equivalence class removes the unphysical longitudinal direction, rather than imposing four independent physical polarization states.

The invariance of the total amplitude is a two-photon fermion Ward identity. Replace ${ϵ}_1^{\ast }$ by $k_1$ and put $q_t=p_1-k_1$, $q_u=p_1-k_2=k_1-p_2$. The external Dirac equations giveAway from propagator poles, $R(q)(/q-m_{\mu })=(/q-m_{\mu })R(q)=I$; the identity extends with the common Feynman prescription. ThereforeThe two terms in the bracket then give $-\bar{v}/{ϵ}_2^{\ast }u$ and $+\bar{v}/{ϵ}_2^{\ast }u$, which cancel. Exchanging photon labels proves the second Ward identity. Thus the sum is unchanged under ${ϵ}_i\mapsto {ϵ}_i+\alpha k_i$ for either photon. Neither diagram is generally gauge-invariant separately. Physically, longitudinal pure-gauge polarization does not couple to the observable scattering amplitude; only the two transverse photon degrees of freedom contribute.

For Compton scattering write the incoming momenta as $p,k$ and outgoing momenta as $p^{\prime },k^{\prime }$, with $p+k=p^{\prime }+k^{\prime }$. The outgoing muon contributes $\bar{u}(p^{\prime })$, the incoming photon contributes $ϵ(k)$ without conjugation, and the outgoing photon contributes ${ϵ}^{\prime \ast }(k^{\prime })$. The two tree-level Compton amplitudes areThese are the lower two diagrams. Their intermediate muon momenta are $p+k$ and $p-k^{\prime }$, with denominators $s-m_{\mu }^2+i0$ and $u-m_{\mu }^2+i0$. The first attaches the incoming photon before the outgoing photon along fermion flow; the second reverses that attachment order. Both contribute at order $e^2$ in the amplitude.

Compton scattering has one incoming and one outgoing muon and one photon on each side; annihilation has an incoming particle-antiparticle pair and two outgoing photons. Accordingly the external spinors/polarizations and physical Mandelstam channels differ, although both arise from the same two-vertex QED matrix element. Crossing symmetry relates them by continuing $p_2\mapsto -p^{\prime }$ and one outgoing photon momentum $k_1\mapsto -k$, with the corresponding external wavefunction replacements. The annihilation $t$ channel becomes the Compton $s$ channel and the other channel becomes its $u$ channel. Identical final photons require a factor $1/2!$ in an annihilation phase-space integral over an otherwise double-counted full final-state region; there is no analogous final-state identical-particle factor for the muon-photon Compton final state. Gauge cancellation holds for the summed Compton amplitude as well.