Yufeng Hao was first-listed author of the 2013 study connecting surface oxygen on copper with growth of large single-crystal graphene domains. The team identified changes in nucleation density and growth behavior.[ref]
This separates making nuclei from expanding existing domains. A treatment can change how many growth centers form as well as how quickly their boundaries advance. Faster growth alone does not guarantee a single crystal if many independently oriented domains are already present.
For an original planar-spacing estimate, suppose nuclei have number density per unit area and each ultimately occupies an area of order . A characteristic spacing is thenAt , . At , . Reducing density by a factor of enlarges this characteristic length by a factor of 100, not .
The estimate assumes a simple two-dimensional allocation of area; it does not describe nucleation timing, anisotropic growth or coalescence in detail. Those omissions matter in a real chemical vapor deposition experiment. The numerical densities are illustrative, not measurements quoted from Hao's paper. Material-growth control and spectroscopic characterization supply complementary evidence about the resulting graphene.
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