Breeder reactor Updated +Created
A nuclear reactor made to produce specific isotopes rather than just consume fissile material to produce electrical power. The most notably application being to produce Plutonium-239 for nuclear weapons from Uranium-238 being irradiated from Uranium-235-created fission.
Gun-type fission weapons don't work with plutonium Updated +Created
Gun-type fission weapons don't work with Plutonium-239 because of the presence of Plutonium-240 as an impurity which leads to fizzle.
Good mentions at: youtu.be/dgBDvnqMkT4?t=252
Plutonium-240 Updated +Created
This isotope shows up as an inevitable contaminant in Plutonium-239 for nuclear weapons, because it emits neutrons too fast and makes it harder to assemble the critical mass without fizzle.
It is the presence of this contaminant that made implosion-type fission weapon a necessity: Section "Gun-type fission weapons don't work with plutonium".
Wikipedia explains that Pu-240 is formed by Pu-239 Neutron capture:
About 62% to 73% of the time when 239Pu captures a neutron, it undergoes fission; the remainder of the time, it forms 240Pu.
so its presence is inevitable.
Weapon grade Plutonium is cheaper than weapon grade Uranium Updated +Created
Because you can generate plutonium-239 from uranium-238 in a breeder reactor, and then separate the plutonium-239 from the Uranium simply by using chemistry methods because you've created an element with different valence electrons.
Isn't it somewhat funny that it is easier to purify a synthetic element than a naturally occurring one?
Weapons-grade nuclear material Updated +Created
For nuclear weapons you need a certain level of isotope purity of either plutonium-239 or uranium-235.
And the easiest way by far to achieve this purity is to produce plutonium-239 in a breeder reactor, which allows you to get it out with much cheaper chemical processes rather than costly isotope separation methods.
fissilematerials.org/ summarizes stockpiles and production status. 20224 Archive.