Eudysmic ratio 1970-01-01
The term "Eudysmic ratio" is not widely recognized in mainstream scientific literature, and it may not refer to a well-defined concept in fields such as biology, medicine, or related sciences. It could be a term used in a specific niche or by a particular research group.
E–Z notation 1970-01-01
E–Z notation is a system used in organic chemistry to describe the stereochemistry of alkenes, specifically the relative positions of substituents attached to the double bond. It is particularly useful when there are multiple substituents on both sides of the carbon-carbon double bond (C=C). The notation is based on the Cahn-Ingold-Prelog priority rules, which assign priorities to different substituents based on atomic number and other factors.
Fischer projection 1970-01-01
A Fischer projection is a two-dimensional representation of a three-dimensional organic molecule, specifically used for depicting the stereochemistry of carbohydrates and amino acids. It was developed by Emil Fischer in the early 20th century. In a Fischer projection, the molecule is represented as a vertical and horizontal arrangement of bonds. The vertical lines represent bonds that project away from the viewer (into the plane of the paper), while the horizontal lines represent bonds that project towards the viewer (out of the plane of the paper).
Gauche effect 1970-01-01
The Gauche effect refers to a conformational preference observed in certain organic molecules, particularly in butane and other alkanes. In these molecules, the Gauche conformation is one where two substituents (or hydrogen atoms) are positioned approximately 60 degrees apart, which can lead to steric interactions and influences on the overall stability of the molecule.
Homochirality 1970-01-01
Homochirality refers to the phenomenon where biological molecules, such as amino acids and sugars, exhibit a preferential uniformity in their chirality, meaning they exist in one specific enantiomeric form rather than a mixture of both. In molecular chemistry, chirality describes the property of a molecule that is not superimposable on its mirror image, much like left and right hands.
Homometric structures 1970-01-01
Homometric structures refer to a concept in geometry and topology that pertains to the idea that two or more shapes can have the same or indistinguishable measurements, such as lengths or angles, despite being different in form or arrangement. In other words, two structures are considered homometric if they can be transformed into one another through a series of isometries (like rotation, translation, or reflection) while maintaining the same metric properties.
Le Bel–Van 't Hoff rule 1970-01-01
The Le Bel–Van 't Hoff rule, also known as the Le Bel-Van 't Hoff rule of stereochemistry, relates to the spatial arrangement of molecules and their optical activity. Specifically, it provides insight into the relationship between the number of stereocenters in a molecule and the number of possible stereoisomers.
Meso compound 1970-01-01
A meso compound is a type of stereoisomer that has multiple stereocenters but is achiral due to an internal plane of symmetry. This means that even though it has chiral centers, the overall molecule is not optically active because one half is a mirror image of the other. Meso compounds typically have symmetrical structures, and this symmetry leads to their achirality.
Molecular configuration 1970-01-01
Molecular configuration refers to the three-dimensional arrangement of atoms within a molecule, particularly how these atoms are bonded together and oriented in space. This includes aspects such as: 1. **Bond Lengths**: The distances between the nuclei of bonded atoms. 2. **Bond Angles**: The angles formed between adjacent bonds at a particular atom. 3. **Dihedral Angles**: The angles between two plane sections formed by four atoms in a molecule.
Mosher's acid 1970-01-01
Mosher's acid, also known as (S)-(+)-2-methyl-2-(trifluoromethyl)benzoic acid, is a chiral auxiliary used in asymmetric synthesis. It is particularly useful for the resolution of enantiomers and for studying stereochemistry due to its ability to form stable complexes with chiral compounds.
Mutarotation 1970-01-01
Mutarotation is a phenomenon observed in solutions of certain carbohydrates, primarily reducing sugars, where the optical rotation of the solution changes over time until it reaches a stable equilibrium. This change in optical rotation occurs due to the interconversion between different anomeric forms of the sugar, particularly in the case of aldoses and ketoses. In aqueous solution, many aldoses can exist in two cyclic forms (anomers): the alpha (α) and beta (β) forms.
Noyori asymmetric hydrogenation 1970-01-01
Noyori asymmetric hydrogenation is a chemical reaction developed by Japanese chemist Ryoji Noyori, which allows for the selective hydrogenation of prochiral ketones and other similar compounds to produce enantiomerically enriched alcohols. This reaction is particularly significant in the field of asymmetric synthesis, where the goal is to produce one specific enantiomer of a chiral product over the other.
Optical rotatory dispersion 1970-01-01
Optical rotatory dispersion (ORD) is a phenomenon in which the optical rotation of a chiral substance varies with the wavelength of light. When plane-polarized light passes through a chiral medium, the plane of polarization is rotated by an amount that depends on the wavelength of the light. This effect is a consequence of the interaction between the light and the chiral molecules in the substance.
Protein primary structure 1970-01-01
Protein primary structure refers to the unique sequence of amino acids that make up a protein. This sequence is determined by the genetic code and is crucial because it ultimately dictates how the protein will fold and function. Amino acids are linked together by peptide bonds to form a polypeptide chain, and the order of these amino acids is specified by the mRNA sequence during translation.
Protein quaternary structure 1970-01-01
Protein quaternary structure refers to the highest level of structural organization in proteins, where two or more polypeptide chains, known as subunits, come together to form a larger, functional protein complex. Each subunit in a quaternary structure can consist of one or more polypeptide chains, and these subunits can be identical (homomeric) or different (heteromeric).
Horme 1970-01-01
Katalepsis 1970-01-01
Katalepsis is a term that originates from ancient Greek philosophy, particularly associated with the Stoics. It refers to the state of having a clear and distinct perception or understanding of an object or concept, often seen as equivalent to true knowledge or certainty. In Stoic thought, katalepsis signifies the moment when an idea or impression is so vivid and compelling that it is taken to be true and is not subject to doubt.
Pentane interference 1970-01-01
Pentane interference typically refers to the impact that pentane, a straight-chain hydrocarbon with five carbon atoms, can have on various chemical analyses, particularly in chromatographic methods. In the context of gas chromatography or mass spectrometry, pentane can co-elute with other compounds, potentially leading to inaccurate results or difficulties in identifying and quantifying other analytes.
Pfeiffer effect 1970-01-01
The Pfeiffer effect refers to an optical phenomenon observed in certain types of materials when they are subjected to mechanical stress. Specifically, it is related to the anisotropic optical properties of certain crystals, particularly in mineralogy and materials science. When a crystal is deformed or stressed, the optical properties—such as birefringence—can change, leading to variations in the light transmission characteristics of the material.
Proline isomerization in epigenetics 1970-01-01
Proline isomerization refers to the process by which the peptide bond involving the amino acid proline can exist in either a cis or trans configuration. This is particularly relevant in the context of protein structure and function, as the isomerization can influence protein folding, stability, and interactions. In epigenetics, proline isomerization can play a role in the regulation of chromatin structure and gene expression.