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Plutonium-240 by Ciro Santilli 35 Updated +Created
This isotope shows up as an inevitable contaminant in Plutonium-239 for nuclear weapons, because it emits neutrons too fast and makes it harder to assemble the critical mass without fizzle.
Wikipedia explains that Pu-240 is formed by Pu-239 Neutron capture:
About 62% to 73% of the time when 239Pu captures a neutron, it undergoes fission; the remainder of the time, it forms 240Pu.
so its presence is inevitable.