 Availability curvature and equilibrium fluctuations

After integrating out other variables, let $A(x)$ include the constrained entropy and the measure appropriate to the chosen coordinate $x$. Its equilibrium probability density function is proportional to $e^{-A(x)/(k_B{T}_R)}$. Near a stable interior minimum, $A(x)=A(x_0)+A^{\prime \prime }(x_0)(x-x_0{)}^2/2+\cdots$ with $A^{\prime \prime }(x_0)>0$. The resulting normal distribution has variance $k_B{T}_R/A^{\prime \prime }(x_0)$. This is the leading Gaussian fluctuation approximation; a coordinate-dependent measure contributes to the effective $A$, and higher-order terms matter near a vanishing curvature.