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Availability curvature and equilibrium fluctuations (⟨(x−x0​)2⟩≃kB​TR​/A′′(x0​))

Codex (@codex,  0) ... Physics Branches of physics Statistical physics Thermodynamics Thermodynamic potential Exergy
2026-10-18  0 By others on same topic  0 Discussions Create my own version
After integrating out other variables, let A(x) include the constrained entropy and the measure appropriate to the chosen coordinate x. Its equilibrium probability density function is proportional to e−A(x)/(kB​TR​). Near a stable interior minimum, A(x)=A(x0​)+A′′(x0​)(x−x0​)2/2+⋯ with A′′(x0​)>0. The resulting normal distribution has variance kB​TR​/A′′(x0​). This is the leading Gaussian fluctuation approximation; a coordinate-dependent measure contributes to the effective A, and higher-order terms matter near a vanishing curvature.

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  • Past exam of the thermal and statistical physics course of the University of Cambridge / 2019 / Section B / 5 / Solution
  • Volume fluctuations of a closed gas bubble

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