 Estimating a quantum expectation value

Prepare a fresh copy of the same quantum state for each trial and measure the same observable. If preparations and readouts are independent, the outcomes $X_i$ are independent and identically distributed random variables with the Born rule probability distribution. Their sample mean is an unbiased estimator of the expectation value:The law of large numbers explains convergence of the sample mean, while the standard error describes its finite-sample spread. It takes four times as many independent trials to halve that standard error. This reduces estimation error; it does not reduce the quantum uncertainty of a single prepared copy.

For the spin expectation value, let $n_{+}$ and $n_{-}$ be the two outcome counts, with $N=n_{+}+n_{-}$. ThenThe binomial distribution gives the exact sampling model. For $\theta =\pi /3$, the standard error is $\hslash \sqrt{3}/(4\sqrt{N})$: approximately $0.1083\hslash$ for $N=16$ and $0.03827\hslash$ for $N=128$. A run can fluctuate away from the predicted mean even as its typical spread decreases.

Repeatedly measuring one surviving system is a different protocol. Under the ideal Lüders rule, outcome $a_r$ leaves $P_r|\psi ⟩/\sqrt{p_r}$ when $p_r>0$. With no intervening change of observable or dynamics moving the state out of that eigenspace, the next projective measurement returns $a_r$ with certainty. Such a record is correlated and does not sample the original Born rule distribution independently. The quantum nondemolition measurement discussion describes this repeatability; fresh quantum state preparations supply the ensemble needed for the estimator above.